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Computer-based automation of concentration measurements with ion-selective electrodes

机译:基于计算机的浓度测量自动化 带有离子选择电极

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摘要

An integrated computer system consisting of an expandableionanalyzer and a PC has been used to automate concentrationmeasurements with ion-selective electrodes (ISEs). The ionanalyzerdetermines ionic concentrations using a reference electrodecoupled with an ISE. The measurements and calibrations arecarried out in a thermostated sample changer equipped with a flowcell. The data obtained by the ionanalyzer are sent via a standardRS 232-C interface to a microcomputer. In this paper, we describethe automatic data acquisition system and the subsequent processingof the measurements. One program (Transorion) automaticallycollects the measurements carried out by the ionanalyzer, giving areal-time graphic representation of the measurement on thecomputer screen. A second program (Graforion) facilitates themanagement of the data stored by the first program, and listing andgraphics of these can be obtained on the printer/plotter. The methodhas been used to study continuous concentration changes in anaqueous solution of potassium iodide.
机译:由可膨胀离子分析仪和PC组成的集成计算机系统已用于通过离子选择电极(ISE)自动进行浓度测量。离子分析仪使用与ISE耦合的参比电极确定离子浓度。测量和校准在装有流通池的恒温进样器中进行。离子分析仪获得的数据通过标准RS 232-C接口发送到微型计算机。在本文中,我们描述了自动数据采集系统以及随后的测量处理。一个程序(Transorion)自动收集由离子分析仪执行的测量值,并在计算机屏幕上实时显示测量值。第二个程序(Graforion)有助于管理第一个程序存储的数据,并且可以在打印机/绘图仪上获得这些数据的列表和图形。该方法已用于研究碘化钾水溶液中浓度的连续变化。

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